Denatonium Benzoate granules

IUPAC name: Phenylmethyl-[2-[(2,6-dimethylphenyl)amino]-2-oxoethyl]-diethylammonium benzoate
Alternative names: Bitrex; phenylmethyl-[2- [(2,6-dimethylphenyl)amino]- 2-oxoetil]-diethylammonium benzoate; Aversion; Denatonii benzoas; N-(2-((2,6-Dimethylphenyl)amino)-2-oxoethyl)-N,N-diethylbenzeneme- thanaminium benzoate; Benzyldiethyl((2,6-xylylcarbamoyl)methyl)ammonium benzoate; benzyl-[(2,6-dimethylphenyl)carbamoylmethyl]-diethyl-azanium; EPA Pesticide Chemical Code 009106; ((2,6-Xylylcarbamoyl)methyl)diethyl benzyl ammonium benzoate; Benzoato de denatonio; Benzoate de denatonium; Anispray; Lidocaine benzyl benzoate; Benzyldiethyl[(2,6-xylylcarbamoyl)methyl]ammonium benzoate; Benzenemethan-aminium, n-(2-((2,6-dimethylphenyl)amino)-2-oxo-ethyl)-n,n-diethyl-, benzoate; benzyl-[(2,6-dimethylphenyl)carbamoylmethyl]-diethyl-azanium benzoate; Ammonium, benzyldiethyl[ (2,6-xylylcarbamoyl)methyl]-, benzoate; Bitter+Plus

General descrpition of the product

Chemical formula: C21H29N2O • C7H5O2
Molar mass: 446,581 g/mol
CAS number: 3734-33-6
EC number: 223-095-2
PubChem: 19518
ChemSpider: 18392
UNII: M5BA6GAF1O
Denatonium benzoate molecule structure
The most bitter chemical compound known, with bitterness thresholds of 0.05 ppm for the benzoate and 0.01 ppm for the saccharide. Dilutions of as little as 10 ppm are unbearably bitter to most humans. Denatonium benzoate is used for denaturation of alcohol, in antifreeze, in nail biting preventions, in respirator mask fit-testing, in animal repellents, in liquid soaps and shampoos. It is not known to pose any long-term health risks. When added, it discourages consumption of harmful alcohols like methanol, and additives like ethylene glycol or in rubbing alcohol. It is also added to many kinds of harmful liquids including solvents such as nail polish remover, paints, varnishes, toiletries and other personal care items, and various other household products. Animals are known to have different sensitivities to the effects of denatonium. It is used in some animal repellents (especially for such large mammals as deer). It has been used to safeguard rat poisons from human consumption, as humans are able to detect denatonium at much lower concentrations than rodents.

Product description

Denatonium benzoate granules 1 kg bottle Denatonium benzoate granules 10 kg box
The fine particles of the product may easily been taken with the air which makes not only the handling person but also the people in the environment tasting the very bitter taste. Therefore a good product has low powder content. The bitter taste is sensible even 500 meters from the place of handling in case of a dusting product. Our product is a dust-free granulate that makes easier and safer to hanle than most of the grades available in the market.
We deliver this product in a recloseable polyethylene bottle, a polyamide bag inside tightly closed containing the product. Therefore the remaining product can be well stored after taking out a part of it.

Specification

Denatonium benzoate granules appearance
Property specification unit of measure
Appearance White odourless granules
Purity ≥ 99,0 % (m/m)
pH 6,5 - 7,5
Chloride content ≤ 0,2 % (m/m)
Drying loss ≤ 1,0 % (m/m)
Sulfate ash content ≤ 0,1 % (m/m)
Loss on ignition ≤ 0,1 % (m/m)
Melting point 136 - 170 °C

Solubility data

Property value unit of measure temperature
Solubility in water 4,5 % (m/v) 20°C
Solubility in ethanol 35,5 % (m/v) 20°C
Solubility in ethylene glycol 40,0 % (m/v) 20°C
Solubility in isopropanol 10,5 % (m/v) 20°C
Solubility in methanol 68,9 % (m/v) 20°C
Solubility in propylene glycol 40,0 % (m/v) 20°C

Safety

Classification in accordance with Regulation (EU-GHS/CLP) No 1272/2008
Acute toxicity (inhalation) Category 4
Skin irritation Category 2
Serious eye damage/irritation Category 2
Specific target organ toxicity - single exposure (oral, dermal, inhalated, lung, respiratory system, central nervous system) Category 3
Classification in accordance with Regulations 67/548/EC or 1999/45/EC
Xn, Harmful R20 Harmful by inhalation.
Xi, Irritative R36/37/38 Irritating to eyes, respiratory system and skin.
Labelling
Warning pictogram
Warning
H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338 IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
Information regarding delivery
The product is not classified as dangerous from delivery (ADR) regulations point of view.

Other information

Customs tariff Nr.: 2924291000
Article Nr.: 93823824 (10 x 1 kg/ carton box)
Article Nr.: 93823033 (1 kg/bottle)
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